Product ID:SCOTCH-GRIP(TM) 4475 PLASTIC ADHESIVE
MSDS Date:12/11/1990
FSC:8040
NIIN:01-036-3487
MSDS Number: BPCBR

MINNESOTA MINING & MFG CO ADHESIVES & SEALERS DIV.

3M CENTER
ST. PAUL, MN 55144-1000
US

Emergency Phone: 612-733-5454

Info Phone: 612-733-5454

Cage: 76381

MINNESOTA MINING AND MFG CO, DBA 3M

SAINT PAUL, MN 55144-1000 US

Telephone: 866-556 5712 / 612-733-1110

Cage: 76381

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 50-60%

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VINYL CHLORIDE-VINYL ACETATE POLYMER

CAS: 9003-22-9

Fraction By Weight: 20-30%

POLYURETHANE

Fraction By Weight: 20-30%

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 2737 MG/KG (MEK)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:LIQUID CONTACT WITH THE EYES CAN CAUSE
SEVERE IRRITATION WHICH COULD RESULT IN PERMANENT DAMAGE. PROLONGED
OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION AND ALLERGIC SKIN
REACTION. VAPOR MAY CAUSE RES PIRATORY SYSTEM IRRITATION AND
LIGHT-HEADEDNESS. MAY CAUSE DIGESTIVE SYSTEM IRRITATION IF
INGESTED.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:TEARING & BLURRED VISION. IRRITATION,
DIZZINESS, HEADACHE, NAUSEA, & IN EXTREME CASES, UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:PEOPLE WITH CHRONIC DISEASES OF THE
SKIN MAY BE AT INCREASED RISK WHEN EXPOSED TO THIS MATERIAL.

First Aid:INHALATION: MOVE PERSON TO FRESH AIR. RESSUSCITATE IF NOT
BREATHING. GET EMERGENCY MEDICAL ASSISTANCE. EYES: FLUSH
IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 10 MINUTES.
GET MEDICAL TREATMEN T. SKIN: WASH AFFECTED SKIN AREAS WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT A PHYSICIAN IF
IRRITATION PERSISTS. INGESTION: DO NOT INDUCE VOMITING: GET
IMMEDIATE MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:20.0F,-6.7C
Lower Limits:1.8
Upper Limits:11.5
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. OVERHEATED, CLOSED
CONTAINERS ADJACENT TO FIRE COULD EXPLODE DUE TO INTERNAL PRESSURE
BUILDUP.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE THE
AREA. CONTAIN THE SPILL. COVER WITH ABSORBENT MATERIALS AS NEEDED.
COLLECT THE SPILLED MATERIAL USING NON-SPARKING TOOLS. PLACE IN DOT
APPROVED METAL CONT AINER, AND SEAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP PRODUCT AND ITS VAPOR AWAY FROM
HEAT, SPARKS, FLAME OR OTHER SOURCES OF IGNITION. THE VAPORS
RELEASED BY THIS PRODUCT CAN EASILY BE IGNITED.
Other Precautions:AVOID PROLONGED BREATHING OF VAPORS. USE ONLY IN
AREAS WITH SUFFICIENT VENTILATION TO MAINTAIN VAPOR CONCENTRATIONS
BELOW RECOMMENDED EXPOSURE LIMITS. PROVIDE LOCAL EXHAUST
VENTILATION IF NECESSARY. A VOID CONTACT WITH SKIN AND EYES.

Respiratory Protection:USE NIOSH APPROVED RESPIRATORS FOR ORGANIC
VAPORS. USE NIOSH/MSHA APPROVED AIRLINE TYPE RESPIRATORS OR HOODS
IN CONFINED AREAS.
Ventilation:SUFFICIENT VENTILATION TO MAINTAIN VAPOR CONCENTRATIONS
BELOW TLVS. PROVIDE LOCAL EXHAUST VENTILATION IF NECESSARY.
Protective Gloves:NEOPRENE OR RUBBER GLOVES
Eye Protection:CHEMICAL SAFETY GOGGLES WITH FACE SHIELD
Other Protective Equipment:USE DISPOSABLE OR IMPERVIOUS CLOTHING IF
WORK CLOTHING CONTAMINATION IS LIKELY. USE PROTECTIVE SKIN CREAM IF
REQUIRED.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING OR USING
THE WASH ROOM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
DO NOT SMOKE IN ANY CHEMICAL HANDLING OR STORAGE AREA. FOOD OR
BEVERAGES SHOULD NOT BE CONSUMED ANYWHERE THIS PRODUCT IS HANDLED
OR STORED. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF THE
REACH OF CHILDREN.

HCC:F2
Boiling Pt:B.P. Text:176F,80C
Vapor Pres:80
Vapor Density:2.5
Spec Gravity:0.95
Viscosity:8500 CPS
Evaporation Rate & Reference:2.7 (WATER=1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, COLORLESS LIQUID, KETONE LIKE ODOR.
Percent Volatiles by Volume:60

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, AMINES AND ALDEHYDES.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON DIOXIDE & CARBON DIOXIDE, AND
SMOKE PARTICLES WHEN SUBJECTED TO EXCESSIVE HEAT OR FLAME.

Waste Disposal Methods:INCINERATE ABSORBED AND BULK PRODUCT AFTER
MIXING WITH FLAMMABLE MATERIAL IN A LICENSED HAZARDOUS WASTE
FACILITY. DISPOSAL SHOULD BE DONE IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL REGULATIONS. EPA H AZARDOUS WASTE NUMBER D001.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.